Search | Engineering

订阅投稿

首页工程期刊工程焦点工程成就工程前沿关于我们 English

资源类型

期刊论文 1617

年份

2024 3

2023 128

2022 153

2021 130

2020 134

2019 125

2018 100

2017 101

2016 72

2015 88

2014 55

2013 43

2012 36

2011 45

2010 47

2009 49

2008 55

2007 68

2006 47

2005 34

展开︾

关键词

遗传算法 9

优化 7

神经网络 7

可持续发展 5

多目标优化 4

机器学习 4

目标识别 4

预测 4

BP神经网络 3

COVID-19 3

算法 3

CAN总线 2

Cu(In 2

GIS 2

GPS 2

HY-2 2

TMS320DM642 2

Weibull分布 2

展开︾

检索范围：

排序：展示方式：

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-basedCO2 capture sorbents

《化学科学与工程前沿（英文）》 2022年第16卷第10期页码 1460-1475 doi: 10.1007/s11705-022-2159-x

摘要： Carbon nanotubes-based materials have been identified as promising sorbents for efficient CO₂ capture in fluidized beds, suffering from insufficient contact with CO₂ for the high-level CO₂ capture capacity. This study focuses on promoting the fluidizability of hard-to-fluidize pure and synthesized silica-coated amine-functionalized carbon nanotubes. The novel synthesized sorbent presents a superior sorption capacity of about 25 times higher than pure carbon nanotubes during 5 consecutive adsorption/regeneration cycles. The low-cost fluidizable-SiO₂ nanoparticles are used as assistant material to improve the fluidity of carbon nanotubes-based sorbents. Results reveal that a minimum amount of 7.5 and 5 wt% SiO₂ nanoparticles are required to achieve an agglomerate particulate fluidization behavior for pure and synthesized carbon nanotubes, respectively. Pure carbon nanotubes + 7.5 wt% SiO₂ and synthesized carbon nanotubes + 5 wt% SiO₂ indicates an agglomerate particulate fluidization characteristic, including the high-level bed expansion ratio, low minimum fluidization velocity (1.5 and 1.6 cm·s^–1), high Richardson−Zakin index (5.2 and 5.3 > 5), and low Π value (83.2 and 84.8 < 100, respectively). Chemical modification of carbon nanotubes causes not only enhanced CO ₂ uptake capacity but also decreases the required amount of silica additive to reach a homogeneous fluidization behavior for synthesized carbon nanotubes sorbent.

关键词： CO₂ capture CNT-based sorbents fluidization SiO₂ nanoparticles fluidized bed reactors

HTML PDF 收藏

A review on research and development of iron-based sorbents for removal of hydrogen sulfide from hot

Jianglong YU, Liping CHANG, Fan LI, Kechang XIE

《化学科学与工程前沿（英文）》 2010年第4卷第4期页码 529-535 doi: 10.1007/s11705-010-0519-4

摘要： In poly-generation and integrated gasification-combined cycle (IGCC) systems for clean energy conversion, it is essential to remove impurities such as sulfur species from hot coal gases prior to entering the subsequent units. This paper provides a comprehensive review on previous studies on high temperature removal of hydrogen sulfide from high temperature coal gases using iron-based sorbents. A two-step desulphurization process for hot coal gas cleanup is highlighted, which is integrated with direct production of elemental sulfur during regeneration of iron-based sorbents in the primary desulphurization step. Different kinetic modeling approaches for sulfidation and regeneration were compared. Limited research on activated carbon supported sorbents was also briefly summarized.

关键词： hot coal gas cleanup iron-based sorbents sulfidation regeneration sulphur recovery

HTML PDF 收藏

Operando modeling and measurements: Powerful tools for revealing the mechanism of alkali carbonate-basedsorbents for CO capture in real conditions

《能源前沿（英文）》 2023年第17卷第3期页码 380-389 doi: 10.1007/s11708-023-0872-x

摘要： Alkali carbonate-based sorbents (ACSs), including Na₂CO₃- and K₂CO₃-based sorbents, are promising for CO₂ capture. However, the complex sorbent components and operation conditions lead to the versatile kinetics of CO₂ sorption on these sorbents. This paper proposed that operando modeling and measurements are powerful tools to understand the mechanism of sorbents in real operating conditions, facilitating the sorbent development, reactor design, and operation parameter optimization. It reviewed the theoretical simulation achievements during the development of ACSs. It elucidated the findings obtained by utilizing density functional theory (DFT) calculations, ab initio molecular dynamics (AIMD) simulations, and classical molecular dynamics (CMD) simulations as well. The hygroscopicity of sorbent and the humidity of gas flow are crucial to shifting the carbonation reaction from the gas−solid mode to the gas−liquid mode, boosting the kinetics. Moreover, it briefly introduced a machine learning (ML) approach as a promising method to aid sorbent design. Furthermore, it demonstrated a conceptual compact operando measurement system in order to understand the behavior of ACSs in the real operation process. The proposed measurement system includes a micro fluidized-bed (MFB) reactor for kinetic analysis, a multi-camera sub-system for 3D particle movement tracking, and a combined Raman and IR sub-system for solid/gas components and temperature monitoring. It is believed that this system is useful to evaluate the real-time sorbent performance, validating the theoretical prediction and promoting the industrial scale-up of ACSs for CO₂ capture.

关键词： CO₂ capture carbonation theoretical modeling operando techniques reaction visualization

HTML PDF 收藏

PSS sorbents for removing trace hydrogen sulfide in methane

Limei ZHONG, Li ZHOU

《化学科学与工程前沿（英文）》 2011年第5卷第3期页码 339-342 doi: 10.1007/s11705-010-0569-7

摘要： Sorbents of the pressure swing sorption process (PSS) to remove trace amount of H S (190 ppm) contained in methane were experimentally studied. The sorbents consist of adsorbent carrier (silica gel or activated carbon) and absorbent which spreads outside the carrier granules’ pores (triethanolamine, TEA or -methyl-2-pyrrolidone, NMP). The results of breakthrough and regeneration tests show that silica gel is more suitable to be the carrier than activated carbon and TEA is more suitable to be the absorbent than NMP. The loaded absorbent could enlarge the sorption capacity of H S considerably. And the BET tests indicate that the absorbent deposits on the surface of the carrier’s pores and can reduce the mesopores’ size and block the micropores.

关键词： pressure swing sorption H₂S methane carrier absorbent

HTML PDF 收藏

Mixed mode properties of CNT reinforced composites using Arcan test rig

Jacob MUTHU

《结构与土木工程前沿（英文）》 2015年第9卷第4期页码 397-404 doi: 10.1007/s11709-015-0321-y

摘要： Composite materials reinforced with carbon nanotubes were mechanical tested using Arcan test rig under Mode-I, Mode-II and mixed mode loading conditions to obtain their fracture properties. The butterfly composite specimens were fabricated with 0.02, 0.05 and 0.1 wt % CNTs. The polyester/CNT composite was fabricated using VRTM (Vacuum Resin Transfer Molding) where the CNTs were first functionalised to reach an optimum properties. Arcan test rig was designed and fabricated to work with the Shimadzu testing machine. The results show that the functionalised CNTs have improved the fracture behavior by acting as bridge between the cracked face. In addition, the fracture properties were not improved for the higher weight fraction of 0.1 wt% CNTs.

关键词： CNT composites Arcan test rig stress intensity factor

HTML PDF 收藏

New nanostructured sorbents for desulfurization of natural gas

Lifeng WANG, Ralph T. YANG

《化学科学与工程前沿（英文）》 2014年第8卷第1期页码 8-19 doi: 10.1007/s11705-014-1411-4

摘要： Desulfurization of natural gas is achieved commercially by absorption with liquid amine solutions. Adsorption technology could potentially replace the solvent extraction process, particularly for the emerging shale gas wells with production rates that are generally lower than that from the large conventional reservoirs, if a superior adsorbent (sorbent) is developed. In this review, we focus our discussion on three types of sorbents: metal-oxide based sorbents, Cu/Ag-based and other commercial sorbents, and amine-grafted silicas. The advantages and disadvantages of each type are analyzed. Possible approaches for future developments to further improve these sorbents are suggested, particularly for the most promising amine-grafted silicas.

关键词： desulfurization natural gas desulfurization hydrogen sulfide sorbent amine-silica sorbent

HTML PDF 收藏

Sponge-based materials for oil spill cleanups: A review

Edward Mohamed Hadji, Bo Fu, Ayob Abebe, Hafiz Muhammad Bilal, Jingtao Wang

《化学科学与工程前沿（英文）》 2020年第14卷第5期页码 749-762 doi: 10.1007/s11705-019-1890-4

摘要： Elimination of leaked oil from aquatic environs has recently gained importance owing to the disasters associated with leakages into marine environments. The need for an environmentally friendly and viable line of action concerning the environs has brought forward numerous affordable, non-toxic, and decomposable materials; further, diverse biomasses for fabricating nano- to micro-scale materials, membranes, and sponges/aerogels have also been incorporated for the elimination and retrieval of oils from water. Moreover, selectivity, sorption capacity, and reusability of these materials after the retrieval of oils are also desired from the viewpoint of sustainability. This review encompasses the recent progress in the field of elimination and retrieval of oil spills using various sponge-based materials.

关键词： membranes sponges reusability sorbents selectivity sorption capacity

HTML PDF 收藏

Erratum to: Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological

《化学科学与工程前沿（英文）》 2022年第16卷第10期页码 1530-1530 doi: 10.1007/s11705-022-2240-5

HTML PDF 收藏

Enhanced activation of peroxymonosulfate by CNT-TiO

Xuemin Hao, Guanlong Wang, Shuo Chen, Hongtao Yu, Xie Quan

《环境科学与工程前沿（英文）》 2019年第13卷第5期 doi: 10.1007/s11783-019-1161-0

摘要： CNT-TiO2 composite is used to activate PMS under UV-light assistance. Superior performance is due to the enhanced electron-transfer ability of CNT. SO4•−, •OH and 1O2 play key roles in the degradation of organic pollutants. In this work, a UV-light assisted peroxymonosulfate (PMS) activation system was constructed with the composite catalyst of multi-walled carbon nanotubes (CNT) - titanium dioxide (TiO2). Under the UV light irradiation, the photoinduced electrons generated from TiO2 could be continuously transferred to CNT for the activation of PMS to improve the catalytic performance of organic pollutant degradation. Meanwhile, the separation of photoinduced electron-hole pairs could enhance the photocatalysis efficiency. The electron spin resonance spectroscopy (EPR) and quenching experiments confirmed the generation of sulfate radical (SO4•−), hydroxyl radical (•OH) and singlet oxygen (1O2) in the UV/PMS/20%CNT-TiO2 system. Almost 100% phenol degradation was observed within 20 min UV-light irradiation. The kinetic reaction rate constant of the UV/PMS/20%CNT-TiO2 system (0.18 min−1) was 23.7 times higher than that of the PMS/Co3O4 system (0.0076 min−1). This higher catalytic performance was ascribed to the introduction of photoinduced electrons, which could enhance the activation of PMS by the transfer of electrons in the UV/PMS/CNT-TiO2 system.

关键词： Peroxymonosulfate activation Carbon nanotubes TiO₂ Water treatment

HTML PDF 收藏

Comparison of CNT-PVA membrane and commercial polymeric membranes in treatment of emulsified oily wastewater

Gang Yi, Xinfei Fan, Xie Quan, Shuo Chen, Hongtao Yu

《环境科学与工程前沿（英文）》 2019年第13卷第2期 doi: 10.1007/s11783-019-1103-x

摘要：

CNT-PVA membrane was fabricated and compared with polymeric membranes.

The separation performance was evaluated by homemade and cutting fluid emulsions.

The three membranes show similar oil retention rates.

CNT-PVA membranes have higher permeation fluxes compared with polymeric membranes.

CNT-PVA membrane shows higher fouling resistance.

关键词： Oily wastewater Microfiltration Carbon nanotube membrane Commercial polymeric membrane

HTML PDF 收藏

High-performance supercapacitors based on Ni

Yunrui Tian, Haishun Du, Shatila Sarwar, Wenjie Dong, Yayun Zheng, Shumin Wang, Qingping Guo, Jujie Luo, Xinyu Zhang

《化学科学与工程前沿（英文）》 2021年第15卷第4期页码 1021-1032 doi: 10.1007/s11705-020-2006-x

摘要： We present a one-step route for the preparation of nickel phosphide/carbon nanotube (Ni P@CNT) nanocomposites for supercapacitor applications using a facile, ultrafast (90 s) microwave-based approach. Ni P nanoparticles could grow uniformly on the surface of CNTs under the optimized reaction conditions, namely, a feeding ratio of 30:50:25 for CNT, Ni(NO ) ·6H O, and red phosphorus and a microwave power of 1000 W for 90 s. Our study demonstrated that the single-step microwave synthesis process for creating metal phosphide nanoparticles was faster and simpler than all the other existing methods. Electrochemical results showed that the specific capacitance of the optimal Ni P@CNT-nanocomposite electrode displayed a high specific capacitance of 854 F·g at 1 A·g and a superior capacitance retention of 84% after 5000 cycles at 10 A·g . Finally, an asymmetric supercapacitor was assembled using the nanocomposite with activated carbon as one electrode (Ni P@CNT//AC), which showed a remarkable energy density of 33.5 W·h·kg and a power density of 387.5 W·kg . This work will pave the way for the microwave synthesis of other transition metal phosphide materials for use in energy storage systems.

关键词： Ni₂P CNT supercapacitors nanocomposites microwave

HTML PDF 收藏

Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing

Jinian Yang, Yuxuan Xu, Chang Su, Shibin Nie, Zhenyu Li

《化学科学与工程前沿（英文）》 2021年第15卷第5期页码 1281-1295 doi: 10.1007/s11705-020-2007-9

摘要： Poor interfacial adhesion and dispersity severely obstruct the continued development of carbon nanotube (CNT)-reinforced epoxy (EP) for potential applications. Herein, hierarchical CNT nanohybrids using nickel phyllosilicate (Ni-PS) as surface decorations (CNT@Ni-PS) were synthesized, and the nanocomposites derived from varied mass fractions of EP and CNT@Ni-PS were prepared. The morphological structures, tribological performances, curing behaviors and thermal properties of EP/CNT@Ni-PS nanocomposites were carefully investigated. Results show that hierarchical CNT nanohybrids with homogeneous dispersion and well-bonded interfacial adhesion in the matrix are successfully obtained, presenting significantly improved thermal and tribological properties. Moreover, analysis on cure kinetics proves the excellent promotion of CNT@Ni-PS on the non-isothermal curing process, lowering the curing energy barrier steadily.

关键词： nickel phyllosilicate surface decoration tribological property curing kinetics thermal performance

HTML PDF 收藏

Al₂O₃ and CeO₂-promoted MgO sorbents for CO₂ capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

《化学科学与工程前沿（英文）》 2018年第12卷第1期页码 83-93 doi: 10.1007/s11705-017-1691-6

摘要： A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

关键词： CO₂ capture MgO sorbents Al₂O₃ CeO₂ flue gas

HTML PDF 收藏

Free vibration analysis of laminated FG-CNT reinforced composite beams using finite element method

T. VO-DUY, V. HO-HUU, T. NGUYEN-THOI

《结构与土木工程前沿（英文）》 2019年第13卷第2期页码 324-336 doi: 10.1007/s11709-018-0466-6

摘要： In the present study, the free vibration of laminated functionally graded carbon nanotube reinforced composite beams is analyzed. The laminated beam is made of perfectly bonded carbon nanotubes reinforced composite (CNTRC) layers. In each layer, single-walled carbon nanotubes are assumed to be uniformly distributed (UD) or functionally graded (FG) distributed along the thickness direction. Effective material properties of the two-phase composites, a mixture of carbon nanotubes (CNTs) and an isotropic polymer, are calculated using the extended rule of mixture. The first-order shear deformation theory is used to formulate a governing equation for predicting free vibration of laminated functionally graded carbon nanotubes reinforced composite (FG-CNTRC) beams. The governing equation is solved by the finite element method with various boundary conditions. Several numerical tests are performed to investigate the influence of the CNTs volume fractions, CNTs distributions, CNTs orientation angles, boundary conditions, length-to-thickness ratios and the numbers of layers on the frequencies of the laminated FG-CNTRC beams. Moreover, a laminated composite beam combined by various distribution types of CNTs is also studied.

关键词： free vibration analysis laminated FG-CNTRC beam finite element method first-order shear deformation theory composite material

HTML PDF 收藏

The role of ions in plasma catalytic carbon nanotube growth: A review

Erik C. Neyts

《化学科学与工程前沿（英文）》 2015年第9卷第2期页码 154-162 doi: 10.1007/s11705-015-1515-5

摘要： While it is well-known that the plasma-enhanced catalytic chemical vapor deposition (PECVD) of carbon nanotubes (CNTs) offers a number of advantages over thermal CVD, the influence of the various individual contributing factors is not well understood. Especially the role of ions is unclear, since ions in plasmas are generally associated with sputtering rather than with growing a material. Even so, various studies have demonstrated the beneficial effects of ion bombardment during the growth of CNTs. This review looks at the role of the ions in plasma-enhanced CNT growth as deduced from both experimental and simulation studies. Specific attention is paid to the beneficial effects of ion bombardment. Based on the available literature, it can be concluded that ions can be either beneficial or detrimental for carbon nanotube growth, depending on the exact conditions and the control over the growth process.

关键词： plasma-enhanced chemical vapor deposition (PECVD) carbon nanotube (CNT) ion bombardment defect healing